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Why is magnesium chloride better than salt?

Published in De-icing Salts Comparison 4 mins read

Magnesium chloride is often considered a superior alternative to traditional rock salt (sodium chloride) primarily due to its significantly reduced corrosiveness and greater environmental friendliness.

Magnesium chloride outperforms common salt in several key areas, making it a more effective and responsible choice for various applications, particularly de-icing.

Why Magnesium Chloride is a Better Choice

Less Corrosive

One of the most significant advantages of magnesium chloride is its less corrosive nature compared to sodium chloride. This is especially true when it's formulated with corrosion inhibitors.

  • Protects Infrastructure: Magnesium chloride is considerably less damaging to metals, vehicles, bridges, and other infrastructure. This reduced corrosiveness translates to extended lifespans for assets and lower maintenance costs over time. Sodium chloride, on the other hand, is notorious for accelerating rust and deterioration.
  • Safer for Equipment: For snow removal equipment and other machinery exposed to de-icers, using magnesium chloride helps mitigate the risk of corrosion, prolonging the life of expensive tools.

Enhanced Environmental Safety

Beyond its impact on infrastructure, magnesium chloride is also a safer choice for vegetation and the broader environment.

  • Vegetation: Unlike sodium chloride, which can dehydrate plants, damage root systems, and contaminate soil along roadways, magnesium chloride has a much reduced impact on plant life. This makes it a more environmentally responsible option for de-icing areas near landscaping or natural habitats.
  • Water Quality: While all de-icers can impact water quality, magnesium chloride generally poses less of a threat to aquatic ecosystems and drinking water sources compared to the higher sodium levels introduced by rock salt. The Minnesota Pollution Control Agency notes that magnesium chloride is slightly less toxic than sodium chloride.

Superior De-icing Performance

Magnesium chloride offers superior performance in cold conditions.

  • Lower Effective Temperature: It remains effective at much colder temperatures than sodium chloride, often working down to -15°F (-26°C). In contrast, sodium chloride's effectiveness significantly diminishes below 20°F (-7°C), requiring more applications or larger quantities to achieve the same result. The City of Madison, WI confirms its effectiveness at these lower temperatures.
  • Faster Action: Magnesium chloride begins to melt ice and snow more quickly, providing safer conditions sooner.

Increased Safety for Pets and People

While responsible use is always advised for any de-icer, magnesium chloride is generally considered a friendlier option for pets and people.

  • Pet Paws: It's typically less irritating to pet paws than harsh rock salt.
  • Ingestion: If accidentally ingested in small quantities, magnesium chloride is often less harmful than sodium chloride, though ingestion should still be avoided. Reputable sources like Wag! Walking categorize magnesium chloride as generally safer than sodium chloride for pets.

Cleaner Application and Residue

Magnesium chloride often leaves less visible white residue than sodium chloride, resulting in cleaner surfaces and reducing the need for post-winter cleanup.

Magnesium Chloride vs. Sodium Chloride Comparison

To summarize the benefits, here's a direct comparison:

Feature Magnesium Chloride (MgCl₂) Sodium Chloride (NaCl)
Corrosiveness Significantly less corrosive to metals, vehicles, and infrastructure Highly corrosive, accelerates rust and damages infrastructure
Effectiveness Effective at much lower temperatures (down to -15°F / -26°C) Less effective at lower temperatures (down to 20°F / -7°C)
Environmental Impact Safer for vegetation and soil, generally less harmful for water quality Can damage plants, leach into soil, and impact water quality
Pet & Human Safety Generally less irritating to paws and less harmful if ingested Can cause irritation, stomach upset, and other issues if ingested
Residue Often leaves less visible residue Can leave significant white, powdery residue
Speed of Action Typically works faster to melt ice Slower action, especially at lower temperatures

Practical Applications and Benefits

Choosing magnesium chloride offers several practical benefits:

  • Reduced Maintenance Costs: Lower corrosion means fewer repairs and replacements for vehicles, bridges, and concrete structures.
  • Improved Environmental Stewardship: A better choice for parks, gardens, and properties located near sensitive ecosystems.
  • Enhanced Safety: More effective de-icing in severe cold leads to safer roads, sidewalks, and driveways.
  • Long-Term Savings: Despite a potentially higher initial cost per pound, the long-term savings from reduced damage and more efficient application often make magnesium chloride a more economical choice.

In conclusion, magnesium chloride presents a superior alternative to traditional salt due to its reduced corrosiveness, better environmental profile, and enhanced performance, particularly in cold conditions.