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What Causes Oil Degradation in Diesel Engines?

Published in Engine Oil Degradation 5 mins read

Oil degradation in diesel engines is a complex and natural process primarily caused by the extreme operational environment, leading to a breakdown of the oil's chemical structure and the depletion of its crucial additives. Factors such as heat, pressure, and stress are significant contributors, constantly attacking the oil and diminishing its protective capabilities over time.

Engine oil in a diesel engine faces a relentless assault from various sources, leading to a loss of its original performance properties. Understanding these causes is key to maintaining engine health and ensuring longevity.

Key Factors Contributing to Oil Degradation

Several primary mechanisms contribute to the breakdown and eventual degradation of engine oil.

1. Thermal and Oxidative Stress

Heat is one of the most destructive factors for engine oil. Diesel engines operate at high temperatures, especially in the piston ring area, turbocharger, and bearings. This intense heat causes the oil to break down chemically. When combined with oxygen, this process is known as oxidation, forming:

  • Varnish and Sludge: Sticky deposits that can block oil passages and hinder heat transfer.
  • Corrosive Acids: These acids can attack metal surfaces, leading to wear and corrosion.
  • Viscosity Increase: Oxidized oil often thickens, making it harder for the oil pump to circulate and reducing its ability to lubricate effectively.

2. Contamination

Diesel engine oil is exposed to numerous contaminants that can severely compromise its integrity and performance.

  • Soot: Incomplete combustion in diesel engines produces fine carbon particles (soot) that, if not effectively dispersed by the oil's additives, can cause abrasive wear and increase oil viscosity. Excessive soot can lead to premature filter clogging.
  • Fuel Dilution: Unburnt fuel can seep past piston rings into the crankcase, thinning the oil and reducing its viscosity and lubricity. This lowers the oil's flash point and can lead to increased wear.
  • Coolant Leaks: Even small amounts of coolant (antifreeze) entering the oil system can form sludge, promote corrosion, and deplete additives. Glycol, a primary component of coolant, reacts with oil to create highly damaging deposits.
  • Dust and Dirt: External contaminants like dust, dirt, and sand can enter the engine through the air intake system or during oil changes. These abrasive particles cause significant wear on critical engine components.
  • Combustion Byproducts: Acids and water vapor are natural byproducts of combustion. While oil is designed to neutralize some acids, excessive exposure or depletion of alkaline additives can lead to acid buildup and corrosion.

3. Additive Depletion

Engine oils are formulated with a sophisticated blend of additives, each performing a specific function. Over the life of the oil, these additives are consumed, used up, or broken down due to the constant heat, pressure, and stress within the engine.

  • Detergents and Dispersants: These additives clean engine surfaces and keep soot and other contaminants suspended in the oil. They get depleted as they bind with contaminants.
  • Anti-wear (AW) and Extreme Pressure (EP) Additives: These form protective films on metal surfaces to prevent contact and wear, gradually being consumed in the process.
  • Antioxidants: These chemicals sacrificialy react with oxygen to prevent oil oxidation, depleting as they do their job.
  • Corrosion Inhibitors: These additives form protective barriers against corrosive acids and water.
  • Viscosity Modifiers (VMs): These long-chain polymer molecules help the oil maintain its viscosity across a range of temperatures. However, they are susceptible to mechanical shear stress, where the intense forces in engine components (like gears and bearings) can permanently break them down, leading to a loss of viscosity and film strength.

4. Mechanical Shear Stress

As mentioned, pressure and stress within moving engine parts, particularly in areas with high shear forces such as valve trains, gear sets, and bearings, can physically degrade the oil. Viscosity modifiers are particularly vulnerable to this mechanical breakdown, leading to a permanent reduction in oil viscosity. This "shearing" effect reduces the oil's ability to maintain a protective film, increasing metal-to-metal contact and wear.

Summary of Oil Degradation Causes

Cause Description Effect on Oil & Engine
Thermal & Oxidation High temperatures and reaction with oxygen Forms sludge, varnish, corrosive acids; increases viscosity
Soot Contamination Incomplete combustion byproducts Abrasive wear, increased viscosity, filter clogging
Fuel Dilution Unburnt fuel entering crankcase Reduces viscosity, lowers flash point, increases wear
Coolant Leaks Antifreeze mixing with oil Forms sludge, promotes corrosion, depletes additives
Dust/Dirt Ingress External particles entering engine Abrasive wear on components
Additive Depletion Consumption of detergents, dispersants, anti-wear agents, antioxidants, etc. Loss of cleaning, protection, and anti-oxidant properties; reduced engine protection
Shear Stress Mechanical forces breaking down polymer chains (viscosity modifiers) Permanent loss of viscosity, reduced film strength, increased wear

Practical Insights & Solutions

  • Regular Oil Analysis: Periodically analyzing engine oil provides insights into its condition, contaminant levels, and additive depletion rates, helping to predict potential engine issues. Learn more about oil analysis benefits.
  • Adhere to OEM Oil Change Intervals: Follow the manufacturer's recommendations for oil change frequency, as these are based on extensive testing under typical operating conditions.
  • Use the Correct Oil Specification: Always use the type and viscosity grade of oil specified by the engine manufacturer (e.g., API, ACEA standards). Using an incorrect oil can accelerate degradation. Explore engine oil specifications.
  • Maintain Engine Systems: Ensure air filters, fuel filters, and cooling systems are in good working order to minimize contamination and control operating temperatures.

By understanding these fundamental causes of oil degradation, engine owners and operators can take proactive steps to extend engine life and maintain optimal performance.