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What is the IUPAC name for Na2S?

Published in Inorganic Chemical Naming 3 mins read

The IUPAC name for Na2S is Sodium sulfide.

Sodium sulfide is a fundamental chemical compound with the chemical formula Na2S. Its name is derived through standard IUPAC (International Union of Pure and Applied Chemistry) nomenclature rules for ionic compounds, which prioritize simplicity and clarity.

Understanding Ionic Compound Naming

Ionic compounds, formed between a metal (cation) and a non-metal (anion), are named by stating the name of the cation first, followed by the name of the anion. The charges of the ions are balanced in the chemical formula, but typically not explicitly stated in the name unless the metal can form multiple different cations.

1. Identifying the Cation

The cation in Na2S is derived from Sodium (Na).

  • Element: Sodium (Na) is an alkali metal, located in Group 1 of the periodic table.
  • Ion Formation: Alkali metals consistently form ions with a +1 charge. Therefore, sodium forms the Na⁺ ion.
  • Naming: Since sodium only forms one stable ion (Na⁺), a Roman numeral is not needed to specify its charge. It is simply named "sodium."

2. Identifying the Anion

The anion in Na2S is derived from Sulfur (S).

  • Element: Sulfur (S) is a non-metal, located in Group 16 of the periodic table.
  • Ion Formation: Non-metals in Groups 15-17 typically gain electrons to achieve a stable noble gas configuration. Sulfur gains two electrons to form the S²⁻ ion.
  • Naming: When a non-metal forms an anion, its name is typically modified to end in "-ide." Thus, the S²⁻ ion is named "sulfide."

3. Combining the Names

By combining the name of the cation (sodium) and the anion (sulfide), we arrive at the IUPAC name for Na2S: Sodium sulfide. The "2" in Na2S indicates that two sodium ions are required to balance the -2 charge of a single sulfide ion, ensuring the compound is electrically neutral.

Key Characteristics of Sodium Sulfide

Sodium sulfide is an important industrial chemical, typically encountered as a yellow solid, often in its hydrated form (e.g., Na2S·9H2O, sodium sulfide nonahydrate). It has various applications due to its reducing and sulfurizing properties.

Feature Description
Chemical Formula Na2S
IUPAC Name Sodium sulfide
Type of Compound Ionic compound
Cation Sodium (Na⁺)
Anion Sulfide (S²⁻)
Appearance Yellow solid (anhydrous); colorless to yellow solid (hydrated forms)
Solubility Highly soluble in water, forming strongly alkaline solutions
Common Uses Pulp and paper industry, leather tanning, textile dyeing, chemical manufacturing

For more details on naming ionic compounds, you can refer to resources like Chem LibreTexts or Wikipedia on Sodium Sulfide.