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Is rock salt corrosive?

Published in Salt Corrosion 3 mins read

Yes, rock salt is corrosive. While often used for de-icing, its chemical composition (primarily sodium chloride) can lead to significant damage over time to various materials and the environment.


Understanding Rock Salt's Corrosive Nature

Rock salt, or sodium chloride (NaCl), causes corrosion through a process known as electrolytic corrosion. When dissolved in water, it creates an electrolyte solution that significantly increases the conductivity of water. This accelerates the electrochemical reaction that leads to the oxidation of metals, commonly known as rusting.

How Rock Salt Corrodes

  • Accelerates Rusting: The chloride ions in rock salt break down the passive protective layer that naturally forms on many metals (like steel), making them more susceptible to rust. This is particularly problematic for vehicles, bridges, and metal infrastructure exposed to salted roads.
  • Damages Concrete: While not causing "rust" in concrete, rock salt can lead to damage. It promotes freeze-thaw cycles, where water absorbed by concrete expands as it freezes, causing cracks and spalling. The salt itself can also exert pressure within the concrete pores, contributing to its breakdown. For more on this, see how salts impact concrete (external link to The Concrete Society).
  • Harms Vegetation and Soil: Salt runoff can elevate sodium levels in soil, interfering with plant nutrient uptake and causing dehydration, leading to stunted growth or even plant death. It can also degrade soil structure.

Comparison to Other De-icers

While corrosive, rock salt is generally considered less corrosive than some other de-icing agents, such as calcium chloride (CaCl2). However, this does not mean it is benign. All chloride-based de-icers carry a risk of corrosion.

De-icing Agent Primary Chemical Corrosiveness (Relative) Common Applications
Rock Salt Sodium Chloride Moderate Roads, sidewalks, driveways
Calcium Chloride Calcium Chloride High Roads, commercial use
Magnesium Chloride Magnesium Chloride Moderate-High Roads, commercial use
Potassium Acetate Potassium Acetate Low Airports, sensitive areas

Mitigating Corrosion from Rock Salt

To minimize the potential damage caused by rock salt, consider these practical steps:

  • For Vehicles:
    • Regular Rinsing: It's advisable to rinse off any accumulated salt residue from vehicles, especially the undercarriage, after the ice has melted or after driving on salted roads. This washes away the corrosive brine.
    • Protective Coatings: Applying waxes or undercarriage sealants can offer a temporary barrier against salt.
  • For Surfaces:
    • Thorough Cleaning: After de-icing, thoroughly rinse driveways, walkways, and other hard surfaces to remove salt residue.
    • Consider Alternatives: For sensitive surfaces like new concrete or flagstone, or near valuable landscaping, opt for less corrosive alternatives like calcium magnesium acetate (CMA), potassium acetate, or even sand for traction.
  • For Landscaping:
    • Protective Barriers: Use burlap or plastic sheeting to shield sensitive plants near salted areas.
    • Watering: Flush the soil with fresh water in the spring to dilute salt concentrations.
    • Choose Salt-Tolerant Plants: If consistent salting is unavoidable, select vegetation known to tolerate higher salt levels.

By understanding the corrosive properties of rock salt and taking proactive measures, you can minimize its detrimental effects on property and the environment.